• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention provides a sharp cutting tool and a method of manufacturing the sharp cutting tool, wherein at least a portion of the sharp cutting tool is formed of a bulk amorphous alloy material.
    公开号:KR20030090661A
    申请号:KR10-2003-7011684
    申请日:2002-03-07
    公开日:2003-11-28
    发明作者:아타칸 페커；스콧 위긴스
    申请人:리퀴드메탈 테크놀러지즈；
    IPC主号:
    专利说明:

    Sharp Cutting Tools {SHARP-EDGED CUTTING TOOLS}
    [2] Conventionally, the shaping and shaving of sharp edges effectively to be durable against mechanical loads, environmentally friendly and low in manufacturing and maintenance costs have been known as a major engineering challenge to produce sharp cutting tools. Accordingly, it is desirable for the blade material to have very good mechanical properties, corrosion resistance, and shaping to tight curvature of 150 angstroms or less.
    [3] Sharp cutting tools are made of various materials, but each material has significant drawbacks. For example, sharp cutting tools made of hard materials such as carbide, sapphire and diamond provide sharp and effective cutting edges, but these materials are quite expensive to manufacture. In addition, the cutting edges of blades made of these materials are very prone to bending due to the low rigidity inherent in the material.
    [4] Sharp cutting tools made of conventional metals, such as stainless steel, can be manufactured at relatively low cost and can be used as disposable products. However, the performance of these blades falls short of those of blades made of more expensive hard materials.
    [5] Recently, it has been proposed to produce cutting tools made of amorphous alloys. Amorphous alloys can provide blades with high strength, flexibility, elastic limits, and corrosion resistance at low cost, but to date, the dimensions and types of blades that can be produced with these materials are dependent on the process required to produce alloys with amorphous properties. Limited by For example, cutting blades made of amorphous alloys are disclosed in US Pat. No. 29,989. However, the alloys disclosed in the prior art must be made into strips having a thickness of 0.002 inches or less, or deposited with a coating on conventional blade surfaces. These manufacturing constraints limit both the type of blades that can be made of amorphous alloys and the sufficient realization of the amorphous properties of these alloys.
    [6] Thus, there is a need for cutting blades having very good mechanical properties, corrosion resistance, and shaping to tight curvatures of 150 angstroms or less.
    [1] The present invention relates to a cutting tool composed of a bulk solidified amorphous alloy, and more particularly to a blade of a cutting tool composed of a bulk solidified amorphous alloy.
    [15] 1 is a side cross-sectional view of a portion of a cutting blade in accordance with the present invention.
    [16] FIG. 2 is a flow chart illustrating a manufacturing process of the cutting tool shown in FIG. 1.
    [7] The subject of the present invention is to provide an improved cutting tool with sharp edges such as blades and surgical scalpels made from bulk solidified amorphous alloys. The present invention includes any cutting blade or tool with improved sharpness and durability.
    [8] In one embodiment, the entire blade of the cutting tool is made of bulk amorphous alloy.
    [9] In another embodiment, only the metal blade of the cutting tool blade is made of bulk amorphous alloy.
    [10] In yet another embodiment, both the blade and the body of the cutting tool are made of bulk amorphous alloy.
    [11] In yet another embodiment, the bulk solidified amorphous alloy element of the cutting tool is designed to withstand up to 2.0% deformation without any plastic deformation. In another such embodiment, the bulk amorphous alloy has a hardness value of at least about 5 GPa.
    [12] In another embodiment of the present invention, the bulk amorphous alloy blade of the cutting tool is safe with a tight curvature of 150 angstroms or less.
    [13] In another embodiment of the present invention, the bulk amorphous alloy is formed into a complex near-net shape by molding or casting. In yet another embodiment, the bulk amorphous alloy cutting tool is obtained from a casting and / or molding without the need for any subsequent processing such as heat treatment or machining.
    [14] The above, the other characteristics, and the advantage of this invention will become clear from the following description mentioned in detail with reference to an accompanying drawing.
    [17] The present invention relates to a cutting tool in which at least a portion of the device is formed from a bulk amorphous alloy material, referred to herein as an amorphous cutting tool.
    [18] 1 is a side view of a cutting tool 10 of the present invention. Generally any cutting tool has a body 20 and a blade 30. In such a cutting tool, the blade 30 is formed as a cutting tool portion that is tapered to the cutting blade forming an end, while the body 20 of the cutting tool transmits the load applied from the cutting tool driving force to the cutting blade 40 of the blade. It is formed into a structure. In addition, as shown in FIG. 1, the cutting tool may optionally include a handle or grip 50 that serves as a stable interface between the cutting tool user and the cutting tool. In this case, the portion of the body 20 to which the handle is attached is referred to as a shank 60. The cutting tool of the present invention is designed with a bulk amorphous alloy composition in which the material for making at least a portion of the body, the blade, or both of the cutting tool. Examples of suitable bulk amorphous alloy compositions are described below.
    [19] While any bulk amorphous alloy can be used in the present invention, in general, a bulk solidified amorphous alloy refers to a group of amorphous alloys that can be cooled at a low cooling rate of less than 500K per second and maintain their amorphous atomic structure substantially. Such bulk amorphous alloys can be prepared with 1.0 mm or more substantially thicker than conventional amorphous alloys having a typical mold thickness of 0.020 mm, which requires a cooling rate of 10 5 K or more per second. Exemplary examples of suitable amorphous alloys are disclosed in US Pat. Nos. 5,288,344, 5,368,659, 5,618,359, and 5,735,975, both of which are incorporated herein by reference.
    [20] One exemplary group of suitable bulk solidified amorphous alloys is represented by the following molecular formula: (Zr, Ti) a (Ni, Cu, Fe) b (Be, Al, Si, B) c, where a is from about 30 to 75 atoms %, B is in the range of about 5 to 60 atomic percent, and c is in the range of about 0 to 50 atomic percent. It should be understood that the above formula does not include all kinds of bulk amorphous alloys. For example, such bulk amorphous alloys can accommodate significant amounts of other transition metal condensate up to about 20 atomic percent of transition metals such as Nb, Cr, V, Co. One exemplary bulk amorphous alloy group is represented by the molecular formula, (Nr, Ti) a (Ni, Cu) b (Be) c, where a ranges from about 40 to 75 atomic percent, b is about 5 to 50 atomic percent And c is in the range of about 5 to 50 atomic percent. One exemplary bulk amorphous alloy composition is Zr 41 Ti 14 Ni 10 Cu 12.5 Be 22.5 .
    [21] While specific bulk solidification amorphous alloys have been described above, they can withstand at least 1.5% strain without any permanent deformation or breakdown, and are at least about 10 ksi-√in, more specifically at least about 20 ksi-√in Any suitable bulk amorphous alloy can be used having high fracture toughness and / or high hardness values of about 4 GPa or more, more specifically about 5.5 GPa or more. Compared with conventional metals, suitable bulk amorphous alloys have a yield strength level of about 2 GPa or more that exceeds the current state of titanium alloys. In addition, the bulk amorphous alloy of the present invention has a density in the range of 4.5 to 6.5 g / cc, thereby high in strength to weight ratio. In addition to the desired mechanical properties, bulk solidified amorphous alloys exhibit very good corrosion resistance.
    [22] Another set of bulk solidified amorphous alloys is a ferrous (Fe, Ni, Co) based composition. Examples of such compositions are described in US Pat. No. 6,325,868 to A. Inoue et. Al., Appl. Phys. Lett., Volume 71, p 464 (1977), (Shen et. Al., Mater. Trans., JIM, Volume 42, p 2136 (2001)), and Japanese Patent Application No. 2000126277 (Publ. # 2001303218 A), which is incorporated herein by reference. One example of such an alloy composition is Fe 72 Al 5 Ga 2 P 11 C 6 B 4 . Another example of such an alloy composition is Al 72 Al 7 Zr 10 Mo 5 W 2 B 15 . These alloy compositions cannot be processed into Zr-based alloy systems, but these materials can still be processed to a thickness of about 0.5 mm or more sufficient to be used herein. In addition, these materials are generally high in density, from 6.5 g / cc to 8.5 g / cc, but the hardness of the material is also high, particularly from 7.5 GPa to 12 GPa or higher, which is particularly preferred. Likewise, these materials have very high elastic deformation limits of 1.2% and yield strengths of 2.5 GPa to 4 GPa.
    [23] In general, crystalline precipitates in bulk amorphous alloys are very detrimental to the properties of the alloy, in particular toughness and stiffness, so it is generally desirable to have a minimum volume. However, ductile metal crystal phases sometimes precipitate in situ during the process of bulk amorphous alloys. These soft precipitates may be desirable for the properties of bulk amorphous alloys, especially toughness and durability. Thus, bulk amorphous alloys containing such preferred precipitates may also be included in the present invention. One exemplary case is disclosed in (C.C. Hays et. Al., Physical Review Letters, Vol. 84, p 2901, 2000), which is incorporated herein by reference.
    [24] In one embodiment of the invention, at least the blade 30 of the cutting tool is formed of one of the bulk amorphous alloy materials described above. In this embodiment, the blades can be manufactured in any dimension and shape, but the sharp cutting edge 40 of the cutting tool preferably has the radius of curvature as small as possible for high performance operation. As a benchmark, diamond surgical scalpel blades can be made with a radius of curvature of the blade of 150 angstroms or less. However, conventional materials encounter various obstacles during the process of cleaning the cutting edge with such a small radius. Conventional materials such as stainless steel have a polycrystalline atomic structure composed of small crystal grains oriented in frequently varying orientations. Because of the anisotropic nature of these crystal structures, the particles in the material respond differently to the shaping action, thereby shaping and manufacturing very effective sharp edges from these crystalline materials, either intact or require significant additional processing. The cost of the final cutting tool increases. Because bulk solidified amorphous alloys do not have a crystal structure, these alloys respond more uniformly to conventional shaping operations such as lapping, chemical, and high energy methods. Thus, in one embodiment, the present invention relates to a cutting tool having a blade made of a bulk amorphous alloy material, wherein the cutting blade 40 of the blade 30 has a radius of curvature of about 150 angstroms or less.
    [25] Because of the small radius of curvature of the cutting edge 40 of these cutting tools, the degree of stiffness of the blade is low, resulting in high levels of deformation during operation. For example, cutting edges made of conventional metals, such as stainless steel, can withstand large deformations only by plastic deformation, resulting in loss of sharpness and flatness. Indeed, conventional metals start to deform plastically at strain levels below 0.6%. On the other hand, cutting blades made of hard materials, such as diamond, are not plastically deformed, but instead they are inherently as low as 1 ksi-sprt (in), which limits their ability to withstand more than 0.6% of deformation. Due to its low fracture toughness. In contrast, because of the unique atomic structure, amorphous alloys are preferably combined with high strength and high fracture toughness, so that cutting blades made from bulk solidified amorphous alloys can easily withstand up to 2.0% deformation without any plastic deformation or chipping. In addition, the bulk amorphous alloy has higher fracture toughness at thinner dimensions (1.0 mm or less), which may be particularly useful for sharp cutting tools. Thus, in one embodiment, the present invention is to provide a cutting tool blade that can withstand a deformation of at least 1.2%.
    [26] While the foregoing discussion focused on the use of bulk solidified amorphous alloys on the blades of cutting tools, bulk solidified amorphous alloys may be the same as the body 20 of a knife or surgical scalpel 10 as shown in FIG. 1. It should be understood that it can also be used as a support for the blade. Such a structure can be used in cutting tools where the sharp edges have different microstructures (which provide higher hardness) than the microstructures of the body support (which provide higher toughness despite the substantially lower hardness). Since the blades must be cut again, the blade material is consumed and the cutting tool must be discarded. In addition, the use of one material for both the body and the blade reduces the likelihood of corrosion, such as through galvanic action of different materials. Finally, since the body and blade of the cutting tool are monolithic, there is no need for an additional structure for attaching the blade to the body so that the force is transmitted to the blade more firmly and precisely, giving the user a harder and more precise feel. Thus, in one embodiment, the invention relates to a cutting tool in which both the blade and the support body are made of bulk amorphous alloy material.
    [27] In addition, if a handle is formed on the body of the cutting tool, other materials such as plastic, wood, etc. may be mounted to the body of the cutting tool to function as the handle grip 50, but the handle and body are made of bulk amorphous alloy. It can also consist of a single unit. In addition, the embodiment of the cutting tool shown in FIG. 1 is shown with a conventional longitudinal knife body 20 with a handle 50 attached to an elongated shank 60 at the end of the body opposite the blade 30. However, the body configuration can be made arbitrarily, and the handle can also be located anywhere on the body of the cutting tool such that force exerted from the user can be transmitted to the cutting tool blade and cutting edge through the handle of the body.
    [28] The cutting tool may be made of a bulk amorphous alloy as described above, but the sharp edge of the cutting tool is manufactured to have a higher hardness and greater durability by coating a hard material such as diamond, TiN, and Sic to a thickness of 0.005 mm. Can be. Because bulk solidified amorphous alloys have elastic limits similar to thin films of hard materials such as diamond, SiC, etc., they are more compatible and provide very effective support for these thin coatings so that the cured coatings do not peel off. Thus, in one embodiment, the present invention is directed to a cutting tool wherein the bulk amorphous alloy blade further comprises an ultra high strength coating (diamond or SiC) to enhance wear resistance.
    [29] Although not described above with respect to the finished cutting tool, it should be understood that the bulk amorphous alloy can be further processed to enhance the aesthetics and color of the cutting tool. For example, the cutting tool may be subjected to any suitable electrochemical process, such as anodizing (electrochemical oxidation of metal). Since such anodizing coatings can also be secondary injected (eg organic and inorganic coloring, lubricity compositions, etc.), additional aesthetic or functional processes can be performed on the anodized cutting tool. Any suitable conventional anodization process can be used.
    [30] The invention also relates to a method of manufacturing a cutting tool from a bulk amorphous alloy. 3 is a flow chart of a process for forming an amorphous alloy product of the present invention, the step of providing a feedstock (step 1), wherein the feedstock is a solid piece in amorphous form for the molding process and the melting temperature for the casting process Or a molten liquid alloy, and then casting the feedstock to a desired shape at a melting temperature or above the melting temperature while cooling (step 2a), or heating the feedstock to a glass transition temperature or higher and molding the alloy into a desired shape. Step (step 2b). Any suitable casting process can be used in the present invention, such as a continuous process such as permanent mold casting, die casting or planar flow casting. One such die casting process is disclosed in US Pat. No. 5,711,363, which is incorporated herein by reference. In addition, blow molding (clamps a portion of the feedstock material and applies a pressure differential on opposite sides of the unclamped area), die-forming (force feed material into the die cavity), and surface features from the replica die. Various molding processes can be used, such as copying of parts. U.S. Pat.Nos. 6,027,586, 5,950,704, 5,896,642, 5,324,368, and 5,306,463, each of which are incorporated herein by reference, disclose methods for forming molded articles from amorphous alloys using glass transition temperatures. . Subsequent processing steps can be used to finish the amorphous alloy product of the present invention (step 3), but the mechanical properties of the bulk amorphous alloy and composition are obtained in cast and / or molded form without the need for subsequent processing such as heat treatment or machining. Can lose. In addition, in one embodiment, the bulk amorphous alloy and its composition are formed into a complex near-net shape in a two step process. In this embodiment, the precision and near-net shape of the casting and molding are maintained.
    [31] Finally, the cutting tool blade is roughly machined to form a preliminary blade, and the final sharp blade is produced by combining one or more conventional lapping, chemical and high energy methods (step 4). As an alternative, the cutting tool (knife and surgical scalpel) may be formed of an amorphous alloy. In this method, a sheet of microcrystalline alloy material is formed in steps 1 and 2, and then cut from the bulk amorphous alloy sheet into a blank at least 1.0 mm thick in step 3 before final shaping and sharpening.
    [32] Although Fig. 1 shows a relatively simple, one-blade knife-type cutting tool, by using a near-net shape process to form a structure made of bulk amorphous metals and compositions, more refined and more advanced mechanical properties are improved. Cutting tools of the design can be achieved.
    [33] For example, in one embodiment, the present invention relates to a cutting tool in which the thickness and / or boundary of the cutting edge changes to form a sawtooth shape. The saw tooth may be formed by any suitable technique, such as a grinding wheel having an axis parallel to the cutting edge. In this process the grinding wheel cuts the metal surface along the cutting edge. As a result, the cutting blade is zigzag as shown to form teeth protruding so that the cutting blade has a sawtooth shape. As an alternative, the sawtooth may be formed by a molding or casting process. The method has the advantage of forming a sawtooth shape in one step. Cutting tools with serrated blades are particularly effective for some types of cutting applications. In addition, the cutting performance of the cutting tool does not depend directly on the sharpness of the cutting blade so that the cutting blade can effectively cut even after the cutting blade is worn down to some extent.
    [34] Although specific embodiments have been described by way of example, those skilled in the art will be able to design other amorphous alloy cutting tools, and that there is a method for manufacturing an amorphous alloy cutting tool according to the literal or equivalent principles of the claims. I can understand.
    权利要求:
    Claims (40)
    [1" claim-type="Currently amended] The blade includes a sharp blade and a body,
    At least one of the blade portion and the body portion is formed of a bulk amorphous alloy material
    Cutting tools.
    [2" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy is represented by the following molecular formula: (Zr, Ti) a (Ni, Cu, Fe) b (Be, Al, Si, B) c, where "a" ranges from about 30 to 75 atomic percent, and " b "ranges from about 5 to 60 atomic percent and" c "ranges from about 0 to 50 atomic percent.
    [3" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy is represented by the following molecular formula: (Zr, Ti) a (Ni, Cu) b (Be) c, where "a" ranges from about 40 to 75 atomic percent and "b" represents about 5 to 50 atoms Cutting tool in the range of about 0 to about 50 atomic percent.
    [4" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy is a cutting tool represented by the following formula, Zr 41 Ti 14 Ni 10 Cu 12.5 Be 22.5 .
    [5" claim-type="Currently amended] The method of claim 1,
    And said bulk amorphous alloy is capable of withstanding at least 1.2% strain without any permanent deformation or breakage.
    [6" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy has a high fracture toughness of at least about 10 ksi-√in.
    [7" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy has a high fracture toughness of at least about 20 ksi-√in.
    [8" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy has a high hardness value of at least about 4 GPa.
    [9" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy has a high hardness value of at least about 5.5 GPa.
    [10" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy is a ferrous metal cutting tool having an elastic limit of about 1.2% or more of the bulk amorphous alloy.
    [11" claim-type="Currently amended] The method of claim 1,
    And said bulk amorphous alloy is a ferrous metal based cutting tool having an elastic limit of at least about 1.2% and said amorphous alloy having a hardness of at least about 7.5 GPa.
    [12" claim-type="Currently amended] The method of claim 1,
    The bulk amorphous alloy is a cutting tool represented by a molecular formula selected from the group consisting of Fe 72 Al 5 Ga 2 P 11 C 6 B 4 and Fe 72 Al 7 Zr 10 Mo 5 W 2 B 15 .
    [13" claim-type="Currently amended] The method of claim 1,
    And at least one of the blade portion and the body portion formed of the bulk amorphous alloy is designed to not plastically deform at a deformation level of at least about 1.2%.
    [14" claim-type="Currently amended] The method of claim 1,
    And at least one of the blade portion and the body portion formed of the bulk amorphous alloy is designed to not plastically deform at a deformation level of at least about 2.0%.
    [15" claim-type="Currently amended] The method of claim 1,
    And the bulk amorphous alloy further comprises a ductile metallic crystalline phase precipitate.
    [16" claim-type="Currently amended] The method of claim 1,
    And a handle mounted on the body portion.
    [17" claim-type="Currently amended] The method of claim 16,
    And the handle is formed of a material selected from the group consisting of plastic, metal and wood.
    [18" claim-type="Currently amended] The method of claim 1,
    At least the blade portion is formed of the bulk amorphous alloy.
    [19" claim-type="Currently amended] The method of claim 1,
    The sharp blade is formed of a bulk amorphous alloy and has a radius of curvature of about 150 angstroms or less.
    [20" claim-type="Currently amended] The method of claim 1,
    The blade is a cutting tool is further coated with a material of high hardness selected from the group consisting of TiN, SiC and diamond.
    [21" claim-type="Currently amended] The method of claim 1,
    The cutting tool is anodized.
    [22" claim-type="Currently amended] The method of claim 1,
    At least one of the blade portion and the body portion formed of the bulk amorphous alloy has a thickness of at least 0.5 mm.
    [23" claim-type="Currently amended] The method of claim 1,
    The cutting tool is a cutting tool of any type of knife or surgical scalpel.
    [24" claim-type="Currently amended] The method of claim 1,
    The cutting tool wherein the sharp blade is serrated.
    [25" claim-type="Currently amended] The blade includes a sharp blade and a body,
    Both the blade portion and the body portion are formed of a bulk amorphous alloy material
    Cutting tools.
    [26" claim-type="Currently amended] In the cutting tool manufacturing method,
    Forming a blank with a bulk amorphous alloy,
    Shaping the blank so that a blade portion and a body portion are formed, and
    Cutting the blade to form a sharp blade
    Cutting tool manufacturing method comprising a.
    [27" claim-type="Currently amended] The method of claim 26,
    The bulk amorphous alloy is represented by the following molecular formula: (Zr, Ti) a (Ni, Cu, Fe) b (Be, Al, Si, B) c, where "a" ranges from about 30 to 75 atomic percent, and " b "ranges from about 5 to 60 atomic percent and" c "ranges from about 0 to 50 atomic percent.
    [28" claim-type="Currently amended] The method of claim 26,
    The bulk amorphous alloy is represented by the following molecular formula: (Zr, Ti) a (Ni, Cu) b (Be) c, where "a" ranges from about 40 to 75 atomic percent and "b" represents about 5 to 50 atoms %, And “c” ranges from about 5 to 50 atomic%.
    [29" claim-type="Currently amended] The method of claim 26,
    The bulk amorphous alloy is represented by the following formula, Zr 41 Ti 14 Ni 10 Cu 12.5 Be 22.5 A cutting tool manufacturing method.
    [30" claim-type="Currently amended] The method of claim 26,
    The bulk amorphous alloy further comprises a soft metal crystalline precipitate.
    [31" claim-type="Currently amended] The method of claim 26,
    Wherein said bulk amorphous alloy is an iron metal based cutting tool having an elastic limit of at least about 1.2% and a hardness of at least 7.5 GPa of the amorphous alloy.
    [32" claim-type="Currently amended] The method of claim 26,
    The bulk amorphous alloy is a cutting tool manufacturing method represented by a molecular formula selected from the group consisting of Fe 72 Al 5 Ga 2 P 11 C 6 B 4 and Fe 72 Al 7 Zr 10 Mo 5 W 2 B 15 .
    [33" claim-type="Currently amended] The method of claim 26,
    And both the blade portion and the body portion are formed of a bulk amorphous alloy.
    [34" claim-type="Currently amended] The method of claim 26,
    And the blade portion is cut such that the blade has a radius of curvature of about 150 angstroms or less.
    [35" claim-type="Currently amended] The method of claim 26,
    And a method for forming one of the blade portion and the body portion comprises one of a method selected from the group consisting of molding and casting.
    [36" claim-type="Currently amended] The method of claim 26,
    And cutting the blank from the bulk amorphous alloy sheet formed by one of the methods selected from the group consisting of molding, casting and thermoplastic casting.
    [37" claim-type="Currently amended] The method of claim 26,
    And cutting the blade portion with a material having a high hardness selected from the group consisting of SiC, diamond, and TiN.
    [38" claim-type="Currently amended] The method of claim 26,
    And mounting a handle to the body portion of the cutting tool.
    [39" claim-type="Currently amended] The method of claim 26,
    And anodizing the cutting tool.
    [40" claim-type="Currently amended] The method of claim 26,
    And forming a sawtooth shape on the sharp blade.
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    同族专利:
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    EP1372918A4|2004-11-03|
    WO2002100611A2|2002-12-19|
    KR100874694B1|2008-12-18|
    JP5877734B2|2016-03-08|
    WO2002100611A3|2003-08-07|
    CN100382939C|2008-04-23|
    JP6171187B2|2017-08-02|
    US6887586B2|2005-05-03|
    EP1372918A2|2004-01-02|
    CN1503714A|2004-06-09|
    JP2016073654A|2016-05-12|
    JP2012166033A|2012-09-06|
    JP2005506116A|2005-03-03|
    AU2002330844A1|2002-12-23|
    JP2009172391A|2009-08-06|
    US20020142182A1|2002-10-03|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    法律状态:
    2001-03-07|Priority to US27433901P
    2001-03-07|Priority to US60/274,339
    2002-03-07|Application filed by 리퀴드메탈 테크놀러지즈
    2002-03-07|Priority to PCT/US2002/006977
    2003-11-28|Publication of KR20030090661A
    2008-12-18|Application granted
    2008-12-18|Publication of KR100874694B1
    优先权:
    申请号 | 申请日 | 专利标题
    US27433901P| true| 2001-03-07|2001-03-07|
    US60/274,339|2001-03-07|
    PCT/US2002/006977|WO2002100611A2|2001-03-07|2002-03-07|Sharp-edged cutting tools|
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